Reading chemical formulas
Formulas

Click for larger imageChemists have a special shorthand way of writing the names of chemicals. For example, water has the formula H2O and salt is NaCl. When iron combines with oxygen in the air to rust, chemists write an equation:
4 Fe + 3 O2 2 Fe2O3. Like any shorthand method of writing, with a few simple rules, the code can be broken and easily read.

This topic will take you through the rules of writing formulas and will help you to read what a chemist means when they write formulas. The next topic Reading chemical equations will help you to read and understand chemical equations.

Formulas
Chemists have formulas or shorthand names for all atoms, ions, molecules and ionic salts known. If a new substance is discovered, a new formulas is used to describe it using the code of formulas writing.

Rule 1:- All substances are made of atoms. There are 92 naturally occurring atoms, each with their own formulas. For example, the simplest atom, hydrogen is written simply as H, while the next atom, helium, is He. A full list of the elements and their formulas can be found in most science texts under the title "Periodic Table of the elements". See the related web sites for more on the elements and their formulas.

All elements are given a symbol that is either a single capital letter or a capital followed by one or two lower case letters. Here is a list of a few of the elements and their formulas that will be used in this topic:

hydrogen
H
sulfur
S
helium
He
silicon
Si
carbon
C
sodium
Na
calcium
Ca
aluminium
Al
chlorine
Cl
oxygen
O
copper
Cu
iron
Fe

Most formulas reflect the English name of the element, but some follow either the Latin or an older name. For example, Cu for copper comes from its Latin name 'cuprum' and Fe for iron comes from the Latin 'ferrum'.

Rule 2: Formulae of molecules. When writing the formula for a molecule, like H2O for water, all the atoms present in the molecule are listed. A subscript number follows any atoms which are present in the molecule more than once. Formulae are written with no gaps and the capitals denote a new element. Click for larger image


In the water molecule there are two hydrogen atoms and one oxygen atom.

Click for larger image

Copper sulfate has the formula:- CuSO4 which represents 1 copper atom, 1 sulfur atom and 4 oxygen atoms.

Here are some more:-

sodium chloride
salt
NaCl
1 sodium and 1 chlorine atom
silicon dioxide
sand
SiO2
1 silicon and 2 oxygen atoms
aluminium oxide
alumina
Al2O3
2 aluminium and 3 oxygen atoms

Rule 3:- Formula of ions. Ions are electrically charged atoms or molecules. They are formed when electrons are either added or removed from an atom or molecule. The charges on ion are shown with a superscript number, if more than one, and a sign. For example, the sodium ion has a charge of 1+, hence its formula is Na+. Oxygen forms a 2- ion, its formula is O2-.

Here are a few more ions and their formulas:

hydrogen ion 1+
H+
chloride ion 1-
Cl-
calcium ion 2+
Ca2+
sulfide ion 2-
S2-
aluminium ion 3+
Al3+
sulfate ion 2-
SO42-

Note: The sulfate ion's formula (SO42-) shows it has 1 sulfur atom and 4 oxygen atoms with an overall charge of 2-.

Rule 4:- Formulae of salts. When ions combine to form salts, the superscript charges are not shown and only the atoms and their rations are displayed, just like for molecules. Sodium chloride and copper sulfate mentioned above are both ionic salts.

Now go to next topic Reading chemical equations which will help you to read and understand chemical equations.

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